Tuesday, June 19, 2012

ADSORPTION AND SOLUBILITY


“Thorium-232 is strongly bound (adsorbed) by soil especially clay soil. The Thorium concentration in the clay particles is about 500,000 % higher than in the water between the clay particles.
So, it cannot be leached out by water and pollute the rivers. Even if the clay soil is washed into the rivers and sea it will not do any harm as the thorium will still be strongly attached (adsorbed) to the clay and will not dissolve into the water.”
Quote Anti-Lynas:
“Lynas’ snake-oil salesman forgot to tell you that the WLP waste will be roasted in concentrated acid. And in that form, thorium is highly soluble. Unquote
The SOLUBILITY of a substance in a solute like water and ADSORPTION of the substance are 2 separate properties and not the same.
In nature Thorium-232 is found in the form of Monazite (Ce,La,Nd,Th)PO4 i.e. the phosphate of Thorium-232. This is completely insoluble in water.
The next most common ore is Thorite (ThSiO4) which has a gram molecular weight of 324.12 gm. This is also completely insoluble in water.
Practically most of the other thorium compounds are artificially created in the laboratory. The most famous is Thorium dioxide (ThO2) which was used as a radiological contrast media and because it is also insoluble, it is administered intravenously as a colloidal dispersion of thorium-232 dioxide (Thorotrast)
Huge doses of 25cc to 50 cc of a 25%solution of Thorium dioxide (Thorotrast) was injected into the vein or artery in the contrast radiological studies.
The other Thorium salts like the fluorides, chlorides, Iodides, sulfides, selenides, tellurides, nitrides, nitrates, sulphates and other complexes are all artificially synthesized.
All of these have varying degrees of solubility in water. The most soluble will be the nitrates, chlorides and to a lesser degree sulphates. As mentioned above, the oxides, silicates and phosphates are insoluble.
Metallic Thorium-232 is of course totally insoluble in water.
However, whether Thorium-232 is in the SOLUBLE OR INSOLUBLE FORM, IT IS STILL STRONGLY ADSORPED BY CLAY AND CANNOT BE LEACHED OUT BY WATER.
The extremely dangerous herbicide Paraquat is a liquid and is extremely soluble in water. Although it is extremely soluble and dangerous, IT IS NOT LEACHED OUT OF THE SOIL and pollute the rivers because it is STRONGLY ADSORPED BY CLAY SOIL JUST LIKE THORIUM-232.
So Lynas can continue their acid roasting of the ore and with the usual procedures taken, it should not be a problem.

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